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- W2040367648 abstract "Abstract Three Ag(I) coordination polymers with flexible long-chain multi-nitrile ligands, [Ag(TDPN)(NO3)]n (1), [Ag(TDPN)(ClO4)]n (2) (TDPN = β,β′- thiodipropionitrile), [Ag2(TCEB)(NO3)2]n (3) (TCEB = 1, 2, 3, 4-tetrakis (2-cyanoethoxy)butane) have been synthesized and structurally characterized by IR spectra and X-ray crystallography. In particular, TCEB is a meso compound. Single-crystal X-ray analysis shows that it contains two chiral carbon atoms with R- and S-configurations. The structures of 1, 2 and 3 consist of a 1-D ladder-like chain, a 2-D boxlike network and a 3-D framework of CdSO4 topology, respectively. IR spectra of the free and coordinated CN groups, the correlation between the counter anions and the topological structures, and the photoluminescent properties of complexes 1–3 are also discussed." @default.
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- W2040367648 date "2004-09-01" @default.
- W2040367648 modified "2023-09-22" @default.
- W2040367648 title "Syntheses, structures and photoluminescent properties of 1D, 2D, 3D silver (I) coordination polymers with flexible long-chain dinitriles and tetranitriles" @default.
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- W2040367648 doi "https://doi.org/10.1016/j.poly.2004.06.035" @default.
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