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- W2040368557 abstract "Abstract The main purpose of this work is proposing a new method of using non-isothermal formal kinetics analysis to predict the lifetime of luminescent complex materials. The Eu(III)-phenanthroline complex doped xerogel has been in situ synthesized by a catalyst-free sol–gel method. The photoluminescence spectra and TG curves of the xerogel verify the formation and decomposition of Eu(III)-phenanthroline complex in xerogel. The decomposition of the xerogel formally occurs in three steps. The Friedman and FWO isoconversional methods and multivariate non-linear regression method are used for formal kinetic analysis. The overall decomposition process below 800 °C is fitted by three-step consecutive reaction. The best fitted model for each step is F n ( n order reaction, the corresponding function f ( α ) is (1 − α ) n ). Correlation coefficient is 0.99956. The lifetime values of xerogel at different temperatures are predicted based on non-isothermal kinetic models by the 5% decomposition of europium organic complex." @default.
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- W2040368557 date "2006-01-01" @default.
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- W2040368557 title "Preparation, thermal decomposition and lifetime of Eu(III)-phenanthroline complex doped xerogel" @default.
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- W2040368557 doi "https://doi.org/10.1016/j.tca.2005.10.003" @default.
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