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- W2040372443 abstract "The structures of ZrBrH0.5 (space group, C2/m) and the isostructural ZrBrH and ZrClH (P3̄m1) have been solved and refined using Guinier powder X-ray data. Each contain tightly bound layers in the sequence XZrZrX, as do the parent ZrX phases. Hydride formation is accompanied by progressive displacement of two layers with respect to the other two, starting with the ABCA sequence in ZrX and terminating with the ABAB sequence in ZrXH. Hydrogen is presumed to lie in tetrahedral metal interstices. The distortion in ZrBrH0.5 produces zigzag chains of distorted tetrahedra with only alternate chains occupied (dHH = 2.73 Å) because otherwise the HH separations would be too short." @default.
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- W2040372443 date "1983-01-01" @default.
- W2040372443 modified "2023-09-25" @default.
- W2040372443 title "The X-ray structures of three zirconium monohalide hydrides" @default.
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- W2040372443 doi "https://doi.org/10.1016/0022-5088(83)90275-8" @default.
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