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- W2040383386 abstract "The first chiral Lewis acid catalyzed enantioselective Friedel−Crafts alkylation of pyrroles with β-CF3 acrylates has been investigated, which afforded various types of chiral trifluoromethylated compounds in excellent yields (90−99%) with high ee’s (up to 99% ee). With the aid of the Friedel−Crafts reaction adduct, optically active trifluorinated heliotridane was successfully constructed." @default.
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- W2040383386 date "2010-02-09" @default.
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- W2040383386 title "Enantioselective Friedel−Crafts Reaction of β-Trifluoromethylated Acrylates with Pyrroles and Its Application to the Synthesis of Trifluorinated Heliotridane" @default.
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- W2040383386 doi "https://doi.org/10.1021/ol100171z" @default.
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