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- W2040383790 abstract "d-N.M.R. Investigations of the Restricted Rotation at the NC(X)-Bonding Fragment. XV. Influence of the Rotational Barrier in the NR2C(X)–R1-Bonding Fragment by Electronic and Steric Substituent Effects. The rotational barriers ΔG≠ of the restricted rotation about partial C,N-double bonds are determined for 4 series of urea-derivatives, and analogous compounds by complete lineshape analysis and approximation equations. Some general conclusions are drawn about the validity range of the approximations independence on the low temperature splitting Δν, the possible corrections within the margin of error and the internal temperature measurement. The dependence of the determined free enthalpies of activation about the effect of heteroatoms X, the NR2-substituents and the electronic and steric influence of the substituents R1 are discussed." @default.
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- W2040383790 date "1982-01-01" @default.
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- W2040383790 title "d-NMR-Untersuchungen der behinderten Rotation am N?C(X)-Bindungsfragment. XV. Beeinflussung der Rotationsbarriere im NR2?C(X)?R1-Bindungsfragment durch elektronische und sterische Substituenteneffekte" @default.
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- W2040383790 doi "https://doi.org/10.1002/prac.19823240106" @default.
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