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- W2040384025 endingPage "2045" @default.
- W2040384025 startingPage "2038" @default.
- W2040384025 abstract "The mechanism of the (bis(phosphanylethyl)phosphane)Pt(2+) catalyzed cyclo-isomerization reaction of 7-methyl-octa-1,6-diene to form 1-isopropylbicyclo[3.1.0]hexane was studied using computational methods. The cyclopropanation step was found to be the turnover-limiting step. The overall reaction proceeds via both a 5-exo and a 6-endo route. W conformations were shown to facilitate cyclopropanation, but do not have any influence on the rate of the 1,2-hydride shifts." @default.
- W2040384025 created "2016-06-24" @default.
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- W2040384025 date "2009-03-16" @default.
- W2040384025 modified "2023-09-23" @default.
- W2040384025 title "Computational Studies on the Platinum(II)-Catalyzed Cycloisomerization of 1,6-Dienes into Bicyclopropanes: A Mechanistic Quandary Evaluated by DFT" @default.
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- W2040384025 doi "https://doi.org/10.1021/om800760x" @default.
- W2040384025 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2700740" @default.
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