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• W2040391186 endingPage "16417" @default.
• W2040391186 startingPage "16410" @default.
• W2040391186 abstract "The zwitterion-coated polyamidoamine (ZC-PAMAM) dendrimer with ammonium and sulfonic acid groups has been synthesized and used as filler for the preparation of PBI-based composite membranes for direct methanol fuel cells. Polybenzimidazole (PBI)/ZC-PAMAM dendrimer composite membranes were prepared by casting a solution of PBI and ZC-PAMAM dendrimer, and then evaporating the solvent. The presence of ZC-PAMAM dendrimer was confirmed by FT-IR and energy-dispersive X-ray spectroscopy (EDS) mapping of sulfur and oxygen elements. The water uptake, swelling degree, proton conductivity, and methanol permeability of the membranes increased with the ZC-PAMAM dendrimer content. For the PBI/ZC-PAMAM-20 membrane with 20 wt% of ZC-PAMAM, it shows a proton conductivity of 1.83 × 10−2 S/cm at 80 °C and a methanol permeability of 5.23 × 10−8 cm2 s−1. Consequently, the PBI/ZC-PAMAM-20 demonstrates a maximum power density of 26.64 mW cm−2 in a single cell test, which was about 2-fold higher than Nafion-117 membrane under the same conditions." @default.
• W2040391186 created "2016-06-24" @default.
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• W2040391186 date "2013-12-01" @default.
• W2040391186 modified "2023-10-06" @default.
• W2040391186 title "Polybenzimidazole/zwitterion-coated polyamidoamine dendrimer composite membranes for direct methanol fuel cell applications" @default.
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• W2040391186 doi "https://doi.org/10.1016/j.ijhydene.2013.09.131" @default.
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