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- W2040391377 abstract "E.s.r. spectroscopy has been employed to detect radicals formed by the oxidation of some alkyl-substituted bis-(4-hydroxyphenyl) sulphides under a variety of conditions. Spectra described include those of the cation-radicals of the parent compounds (obtained by oxidation with Lewis acids) and those of sulphur-substituted phenoxyl radicals (from reaction of the parent compounds with CeIV or PbIV) and semiquinones (from reaction with FeIII in basic solution). Secondary radicals detected in some instances include stable semiquinones and hydroxylated semiquinones formed in basic solution in the presence of oxygen. The mechanisms of their formation are discussed. Results of molecular orbital calculations on some of the sulphur-containing radicals are reported." @default.
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- W2040391377 date "1976-01-01" @default.
- W2040391377 modified "2023-09-26" @default.
- W2040391377 title "An e.s.r. investigation of radical reactions of some sulphur-containing phenolic antioxidants" @default.
- W2040391377 doi "https://doi.org/10.1039/p29760001267" @default.
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