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• W2040391381 abstract "The reactions of [Pd(dppp)(edt)] 1 or [Pd(dppp)(pdt)] 2 (edt2− = ethane-1,2-dithiolate, pdt2− = propane-1,3-dithiolate, dppp = 1,3-bis(diphenylphosphino)propane) with oxygen or elemental Se under different reaction conditions gave rise to a series of polynuclear palladium complexes. The oxidation of 1 by oxygen in alkaline DMF solution yielded a dinuclear complex with sulfinato ligand, [Pd2(O2SCH2CH2SO2)(edt)(dppp)] 3, while that of 2 afforded a hexanuclear complex, [Pd6(pdt)6] 4. The molecular structure of 3 consists of two fragments [Pd(O2SCH2CH2SO2)] and [Pd(dppp)]2+, which are linked by an edt2− bridging ligand. The structure of 4 is made up of [Pd(pdt)] units forming a cyclic neutral complex, of which the Pd6S12 core possesses pseudo D6d symmetry and six Pd atoms form a nearly regular six-membered ring with Pd⋯Pd distances ranging from 3.050 to 3.090 A. The treatment of 2 with elemental Se in the ratios 2∶1 and 1∶1 generated [Pd2(dppp)2(pdt)]Cl25 and [Pd3(dppp)2(pdt)2]Cl26, respectively. The molecular structure of 5 and 6 can be considered as two fragments [Pd(dppp)]2+ linked by pdt2− and [Pd(pdt)2]2−, respectively. The reaction of 1 with 0.5 equivalent Se led to formation of [Pd2(dppp)2(edt)]Cl27. The molecular structure of 7 is quite similar to that of 5. All palladium atoms in the complexes are four-co-ordinated with distorted square-planar geometry. The complexes 1, 3–7 have been characterized by NMR, IR and electronic spectra." @default.
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• W2040391381 date "2000-01-01" @default.
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• W2040391381 title "A new access to palladium–phosphine chemistry. Formation of polynuclear palladium compounds via the oxidation of ligands in simple palladium(II) complexes" @default.
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• W2040391381 doi "https://doi.org/10.1039/a908788e" @default.
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