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- W2040394895 abstract "Pb2+ ion exchange in N-octadecanoyl-l-alanine Langmuir−Blodgett film has been investigated by FTIR spectroscopy. The condensation effect of Pb2+ gives rise to a significant increase in the hydrogen-bonding interaction between adjacent molecules, so that a complete ion exchange occurs after Pb2+ penetrates into the Langmuir−Blodgett film through structure defects. FTIR studies demonstrate that two types of metal complexes are formed with different headgroup coordination and chain orientation: (1) the chelating bidentate complex is formed between Pb2+ ions and carboxylate groups, and the C−C−C planes of the corresponding hydocarbon chains are favorably oriented parallel to the film substrate; (2) the bridging bidentate complex is formed between Pb2+ ions and carboxylate groups, and the C−C−C planes are preferentially oriented perpendicular to the film substrate. The orthogonal orientation of the two types of C−C−C planes is considered to be the probable reason for the monolayer collapse in the presence of ..." @default.
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- W2040394895 date "2001-06-13" @default.
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- W2040394895 title "Molecular Structure of Lead <i>N</i>-Octadecanoyl-<scp>l</scp>-alaninate Langmuir−Blodgett Film" @default.
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- W2040394895 doi "https://doi.org/10.1021/jp010157t" @default.
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