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- W2040394909 abstract "Anionic polymerization of para-xylelene, p-X, may be initiated in solution at a low temperature (∼−70°C) by electron-transfer process. The spontaneous formation of diradicals through dimerization of p-X monomers is too slow at these temperatures to initiate the radical polymerization of p-X. The anionic polymerization yields a living poly(p-xylelene) which is capable of growing further by the addition of vinyl pyridine, VP. In this way block polymers PVP-PpX-PVP were prepared. Alternatively, the addition of p-X monomers to living polystyrene, PS, or living poly(vinyl pyridine), PVP, yields at low temperatures the block polymers PpX-PS-PpX or PpX-PVP-PpX. The block polymers prepared by this approach were isolated and characterized. Even small blocks of PpX attached to polystyrene or poly(vinyl pyridine) make the resulting polymers insoluble in boiling solvents below 200°C." @default.
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- W2040394909 date "1976-09-01" @default.
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- W2040394909 title "Block polymers of poly(para-xylelene) and polystyrene or poly(vinyl pyridine) prepared by anionic polymerization" @default.
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- W2040394909 doi "https://doi.org/10.1016/0032-3861(76)90037-9" @default.
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