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- W2040398922 abstract "Abstract The original structure of 1,3,5-trimethyl-2,4,6-trinitrobenzene (TNM) is composed of separate planar layers with hexagonal pseudo-symmetry, like a prismatic single crystal. These layers are parallel to (20) and the interlayer distance is greater than the standard spacing for two benzene rings. NO 2 group planes and the tallying benzene ring are nearly normal. This and the methyl group resonance minimize the interlayer oxygen-hydrogen distances of two symmetrical molecules in separate layers. Crystal data: triclinic, space group P, a = 8.268(1) A, b = 8.7890(5) A, c = 9.932(1) A, α = 108.12(1)°, β= 113.25(1)°, γ = 95.19(1)°, V = 549.7(2) A 3 , Z = 2, R(F) = 5.1 %, 1 822 observed reflections ¦F 0 2 > 3 σ(F 0 2 )" @default.
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- W2040398922 date "1997-11-01" @default.
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- W2040398922 title "Crystal structure of 1,3,5-trimethyl-2,4,6-trinitrobenzene, trisubstituted picryl group" @default.
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- W2040398922 doi "https://doi.org/10.1016/s1251-8069(97)88175-4" @default.
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