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• W2040420930 abstract "Radioactive 137Cs may be removed from nuclear waste aqueous solutions by precipitation. Alkali metal salt solubility trends show that the Cs+ salts have the largest range of solubilities for all of the alkali metal salts and that Cs+ should be the most likely ion of the group to form a precipitate in solution. The tetraphenylborate anion (B(C5H5)4−, TPB) precipitates Cs+ as the insoluble CsTPB. However, there are a number of problems associated with this compound and another precipitating agent is needed. A potential substitute is the cobalt dicarbollide anion (Co(B9C2H11)2−, CDC) which forms a slightly more soluble compound, CsCDC. The anion:cation volume ratios for several simple alkali metal salts, when compared with their solubility values, indicate that forces within the solid crystal control solubility. Similar comparisons for the TPB and CDC anions indicate that the solubilities are controlled by the hydrophobic nature of the anion. Some requirements are proposed for an anion to form a precipitate with Cs+." @default.
• W2040420930 created "2016-06-24" @default.
• W2040420930 creator A5086912917 @default.
• W2040420930 date "1995-03-01" @default.
• W2040420930 modified "2023-10-16" @default.
• W2040420930 title "The solubilities of the alkali metal salts and the precipitation of Cs+ from aqueous solution" @default.
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• W2040420930 doi "https://doi.org/10.1016/0010-8545(94)01123-s" @default.
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