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- W2040421683 abstract "NiFe thin film alloys with nanometer-scale spatially periodic composition modulations have been electrodeposited in the uniform injection cell (UIC) by oscillating the electrolyte flow rate. [See, Medina and Schwartz, J. Electrochem. Soc. 142, 451, 457, L46 (1995) for a description of the UIC.] The flow-induced composition modulated alloys were made using flow oscillation frequencies ω ≤ 0.05 Hz and galvanostatic deposition at −10 mA cm−2. Flow-induced periodicity wavelengths (Λ) as small as 55 nm were measured using stripping voltammetry. The experimental results showed that Λ had the expected inverse dependence on the flow oscillation frequency. The electrochemical response of the NiFe plating system was found to be out of phase with the low frequency (quasi-steady) flow modulations, a result that reiterates the anomalous nature of NiFe codeposition and the important role that careful hydrodynamic impedance studies could possibly play in analyzing the system." @default.
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- W2040421683 date "1997-01-01" @default.
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- W2040421683 title "Electrodeposition of flow-induced composition modulated NiFe alloys in the uniform injection cell" @default.
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- W2040421683 doi "https://doi.org/10.1016/s0013-4686(97)00006-6" @default.
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