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- W2040432751 abstract "Tetravalent terbium perovskites, BaTbO3 and SrTbO3, were prepared, and their magnetic susceptibilities and electron paramagnetic resonance (EPR) spectra were measured. Both the compounds showed antiferromagnetic transitions at 32.7 and 30.5 K, respectively. The effective magnetic moment of terbium is 7.96 μB, which is very close to the theoretical value of the Tb4+ ion. The EPR spectra could be measured at room temperature. The spectra were broad and the g-values of BaTbO3 and SrTbO3 were 2.00 and 1.97, respectively. These results also show that the oxidation state of terbium is not trivalent, but tetravalent. The deviation of the g-value from 2.00 for SrTbO3 is due to the large crystal field distortion from octahedral symmetry around the terbium ion." @default.
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- W2040432751 date "1992-09-01" @default.
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- W2040432751 title "Magnetic susceptibility and electron paramagnetic resonance studies of tetravalent terbium ions in BaTbO3 and SrTbO3" @default.
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- W2040432751 doi "https://doi.org/10.1016/0022-4596(92)90163-p" @default.
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