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- W2040444779 abstract "Abstract It is demonstrated using gamma-radiolytic and photolytic techniques that, when O2•- is produced in the presence of catalytic amounts of iron(II) and iron(III) complexes depolymerization of xanthan in aqueous solution occurs. The use of these techniques also allows a quantitative measurement of the efficiency of conversion of O2•- to •OH in these systems to be made, with the assumption that •OH is the most likely depolymerizing species present. Using pulse radiolysis and oxidative-reductive depolymerization, the effects of some common anions on the degradation process have been correlated with the reactivities of their related free radicals with xanthan. The effects of other parameters such as ionic strength and temperature on xanthan depolymerization are also detailed" @default.
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- W2040444779 date "1985-06-01" @default.
- W2040444779 modified "2023-09-23" @default.
- W2040444779 title "Depolymerization of xanthan by iron-catalysed free radical reactions" @default.
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- W2040444779 doi "https://doi.org/10.1016/0141-8130(85)90023-6" @default.
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