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- W2040450401 abstract "The application of a wavefront-shearing optical interferometer to diffusion measurements in aqueous solutions of mono-, di-, and tri-ethanolamines is described. This technique is extremely accurate in determining diffusivities, and the results are compared with measurements made with a Gouy interferometer. The large differences between the experimentally determined diffusion coefficients at infinite dilution and those predicted by existing semi-empirical equations are shown to be due in part to the inadequacy of these equations, and in part to the hydration of the ethanolamines in solution. It is recommended that, in the use of the semi-empirical equations, molecular irregularities in solution be allowed for by recalculation of the solute molecular volume on the basis of a hydrated molecule." @default.
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- W2040450401 date "2007-05-04" @default.
- W2040450401 modified "2023-10-18" @default.
- W2040450401 title "Diffusion measurements for ethanolamine-water systems with a wavefront-shearing interferometer" @default.
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- W2040450401 doi "https://doi.org/10.1002/jctb.5010170903" @default.
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