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• W2040457475 startingPage "214" @default.
• W2040457475 abstract "Isomerizations of the alkoxy radicals formed from the OH radical reactions with n-butane through n-octane and n-pentane-d12 through n-octane-d18 have been studied in the presence of NO at 296 ± 2 K and 740 Torr total pressure of air. In addition to carbonyls of the same carbon number as the alkane precursors, the previously predicted δ-hydroxycarbonyls were detected by direct air sampling atmospheric pressure ionization triple quadrupole mass spectrometry. The formation yields of carbonyl compounds containing the same number of carbons as the parent n-alkane decreased with increasing carbon number in the n-alkane, while the hydroxycarbonyl/carbonyl formation yield ratios increased markedly from n-butane through n-octane, in agreement with previous theoretical predictions." @default.
• W2040457475 created "2016-06-24" @default.
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• W2040457475 date "1996-01-01" @default.
• W2040457475 modified "2023-10-03" @default.
• W2040457475 title "Alkoxy Radical Isomerization in the OH Radical-Initiated Reactions of C₄−C₈ <i>n</i>-Alkanes" @default.
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• W2040457475 doi "https://doi.org/10.1021/jp952036x" @default.
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