FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040463795> ?p ?o ?g. }

• W2040463795 endingPage "1550" @default.
• W2040463795 startingPage "1541" @default.
• W2040463795 abstract "The lowest excited triplet (T1) state of 3,3′-biisoquinoline(dicyano)platinum(II), [Pt(CN)2(i-biq)] was examined by time-resolved electron paramagnetic resonance (TREPR) and optical techniques in comparison with that of a ligand 3,3′-biisoquinoline (i-biq). Trans and cis i-biqs were assigned from obtained and calculated zero-field splittings (zfs') in the T1 state. The zfs parameter D increased with complex formation from 2.66 to 4.66 GHz in a rigid dimethylformamide solution; the polarization pattern of the spectrum was very different between the ligand and the complex. The triplet lifetime (ca. 1 s) of i-biq is also remarkably shortened in the complex (ca. 2 ms). These facts were analyzed in terms of the spin-orbit coupling (soc) between T1 (ππ*) and 1,3dπ*. From the analyses, the soc matrix element and the magnitude of delocalization of π* electrons over the Pt atom are obtained as 65 cm-1 and 0.02, respectively. The solvent dependences of the D value and the triplet lifetime also support the importanc..." @default.
• W2040463795 created "2016-06-24" @default.
• W2040463795 creator A5025217672 @default.
• W2040463795 creator A5040800973 @default.
• W2040463795 creator A5052816255 @default.
• W2040463795 creator A5067680542 @default.
• W2040463795 creator A5073660501 @default.
• W2040463795 creator A5090359251 @default.
• W2040463795 date "2000-07-01" @default.
• W2040463795 modified "2023-09-26" @default.
• W2040463795 title "Studies of the Lowest Excited Triplet State of 3,3^′-Biisoquinoline(dicyano)platinum(II) [Pt(CN)₂(<b><i>i</i></b>-biq)] by Means of Time-Resolved Electron Paramagnetic Resonance and Optical Spectroscopy" @default.
• W2040463795 cites W1597530320 @default.
• W2040463795 cites W1968787569 @default.
• W2040463795 cites W1969289891 @default.
• W2040463795 cites W1970393749 @default.
• W2040463795 cites W1971784013 @default.
• W2040463795 cites W1977477606 @default.
• W2040463795 cites W1984032910 @default.
• W2040463795 cites W1986162594 @default.
• W2040463795 cites W1999157871 @default.
• W2040463795 cites W2001744449 @default.
• W2040463795 cites W2001903641 @default.
• W2040463795 cites W2007230150 @default.
• W2040463795 cites W2012372382 @default.
• W2040463795 cites W2012582858 @default.
• W2040463795 cites W2016029348 @default.
• W2040463795 cites W2017100858 @default.
• W2040463795 cites W2020182873 @default.
• W2040463795 cites W2021432892 @default.
• W2040463795 cites W2031795491 @default.
• W2040463795 cites W2035735395 @default.
• W2040463795 cites W2042754172 @default.
• W2040463795 cites W2043755111 @default.
• W2040463795 cites W2044404910 @default.
• W2040463795 cites W2049023671 @default.
• W2040463795 cites W2052752040 @default.
• W2040463795 cites W2054355767 @default.
• W2040463795 cites W2074053115 @default.
• W2040463795 cites W2081626220 @default.
• W2040463795 cites W2091104035 @default.
• W2040463795 cites W2091679306 @default.
• W2040463795 cites W2095468503 @default.
• W2040463795 cites W2127336290 @default.
• W2040463795 cites W212929038 @default.
• W2040463795 cites W2148307991 @default.
• W2040463795 cites W2152610028 @default.
• W2040463795 cites W2264368894 @default.
• W2040463795 cites W2314587361 @default.
• W2040463795 cites W2949725023 @default.
• W2040463795 doi "https://doi.org/10.1246/bcsj.73.1541" @default.
• W2040463795 hasPublicationYear "2000" @default.
• W2040463795 type Work @default.
• W2040463795 sameAs 2040463795 @default.
• W2040463795 citedByCount "9" @default.
• W2040463795 countsByYear W20404637952012 @default.
• W2040463795 countsByYear W20404637952021 @default.
• W2040463795 crossrefType "journal-article" @default.
• W2040463795 hasAuthorship W2040463795A5025217672 @default.
• W2040463795 hasAuthorship W2040463795A5040800973 @default.
• W2040463795 hasAuthorship W2040463795A5052816255 @default.
• W2040463795 hasAuthorship W2040463795A5067680542 @default.
• W2040463795 hasAuthorship W2040463795A5073660501 @default.
• W2040463795 hasAuthorship W2040463795A5090359251 @default.
• W2040463795 hasConcept C113196181 @default.
• W2040463795 hasConcept C11413529 @default.
• W2040463795 hasConcept C121332964 @default.
• W2040463795 hasConcept C161790260 @default.
• W2040463795 hasConcept C178790620 @default.
• W2040463795 hasConcept C181500209 @default.
• W2040463795 hasConcept C184779094 @default.
• W2040463795 hasConcept C185592680 @default.
• W2040463795 hasConcept C41008148 @default.
• W2040463795 hasConcept C48103436 @default.
• W2040463795 hasConcept C518104683 @default.
• W2040463795 hasConcept C76766466 @default.
• W2040463795 hasConceptScore W2040463795C113196181 @default.
• W2040463795 hasConceptScore W2040463795C11413529 @default.
• W2040463795 hasConceptScore W2040463795C121332964 @default.
• W2040463795 hasConceptScore W2040463795C161790260 @default.
• W2040463795 hasConceptScore W2040463795C178790620 @default.
• W2040463795 hasConceptScore W2040463795C181500209 @default.
• W2040463795 hasConceptScore W2040463795C184779094 @default.
• W2040463795 hasConceptScore W2040463795C185592680 @default.
• W2040463795 hasConceptScore W2040463795C41008148 @default.
• W2040463795 hasConceptScore W2040463795C48103436 @default.
• W2040463795 hasConceptScore W2040463795C518104683 @default.
• W2040463795 hasConceptScore W2040463795C76766466 @default.
• W2040463795 hasIssue "7" @default.
• W2040463795 hasLocation W20404637951 @default.
• W2040463795 hasOpenAccess W2040463795 @default.
• W2040463795 hasPrimaryLocation W20404637951 @default.
• W2040463795 hasRelatedWork W1971207469 @default.
• W2040463795 hasRelatedWork W1992410727 @default.
• W2040463795 hasRelatedWork W2023082097 @default.
• W2040463795 hasRelatedWork W2029698082 @default.
• W2040463795 hasRelatedWork W2069214071 @default.
• W2040463795 hasRelatedWork W2080869919 @default.
• W2040463795 hasRelatedWork W2085329475 @default.

• next