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- W2040472636 abstract "Interaction of trimethyl phosphate (TMP) with metal perchlorates in triethyl orthoformate leads to the formation of cationic complexes of the types: [M(TMP)6]n+ (M = Mg(II), Ca(II), Al(III), Cr(III), Fe(III), [Ce(TMP)6(OClO3]2+, [M(TMP)5]2+ (M = Mn, Fe, Co, Cu, Zn) and [Ni(TMP)5 (H2O)]2+. The pentacoordinated Mn(II), Fe(II), Co(II) and Cu(II) complexes are of the high-spin type. The new complexes were characterized by means of spectral, magnetic, conductance and X-ray powder diffraction studies. A distorted Oh symmetry was assigned to the hexacoordinated cationic complexes, and a symmetry closer to C4v than D3h to the pentacoordinated complex cations. Solid-state and solution electronic spectra are discussed and compared to those reported for complexes of neutral organophosphoryl esters. Steric effects influencing the stabilization of higher-coordinated cationic metal complexes become more favorable as the number of methoxy substituents in ligands of the type RR′2PO(R,R′ = CH3 or CH3O) increases." @default.
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- W2040472636 date "1970-04-01" @default.
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- W2040472636 title "Penta-, hexa-, and hepta- coordinated cationic metal complexes of trimethyl phosphate" @default.
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- W2040472636 doi "https://doi.org/10.1016/0022-1902(70)80102-6" @default.
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