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- W2040474515 abstract "Abstract The role of ceria, niobium and molybdenum oxides on the promotion of the NO reduction by CO was studied. A bifunctional mechanism was discussed as a function of both the nature of interaction between metal oxide and palladium and the redox properties of each metal oxide. The NO dissociation was better on the Pd/MoO 3 /Al 2 O 3 catalyst than on the Pd/CeO 2 /Al 2 O 3 and Pd/Nb 2 O 5 /Al 2 O 3 catalysts. The explanation for the very high N 2 production on Pd–Mo catalyst during the TPD analysis may be attributed to the NO+Me δ + stoichiometric reaction. The promoting effect of a reducible oxide for the NO+CO reaction at low temperature can be ascribed mainly to its easiness for a redox interchange and its interaction with the noble metal particles. This would increase the surface redox ability and favor the dynamic equilibrium needed for high N 2 selectivity." @default.
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- W2040474515 date "2001-03-01" @default.
- W2040474515 modified "2023-09-22" @default.
- W2040474515 title "The nature of metal oxide on adsorptive and catalytic properties of Pd/MeOx/Al2O3 catalysts" @default.
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- W2040474515 doi "https://doi.org/10.1016/s0926-860x(00)00824-3" @default.
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