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- W2040475019 abstract "A family of supramolecular reagents containing two different binding sites, pyridine and amino-pyrimidine, were allowed to react with iodo- or bromo-substituted benzoic acids in order to assemble individual molecules into larger architectures with precise intermolecular interactions, using a combination of hydrogen- and halogen-bonds. The hydrogen-bond based amino-pyrimidine/carboxylic acid or amino-pyrimidinium/carboxylate synthons are responsible for the assembly of the primary structural motif in every case (7/7 times, 100% supramolecular yield), while I···N, Br···N, and I···O, halogen bonds play a structural supporting role by organizing these supermolecules into extended 1D and 2D architectures (5/7 times, 71% supramolecular yield). These results illustrate how two different noncovalent interactions can be employed side-by-side in the reliable construction of extended molecular solid-state networks with predictable connectivity and dimensionality." @default.
- W2040475019 created "2016-06-24" @default.
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- W2040475019 creator A5091742645 @default.
- W2040475019 date "2008-11-26" @default.
- W2040475019 modified "2023-10-06" @default.
- W2040475019 title "Supramolecular Synthesis Based on a Combination of Hydrogen and Halogen Bonds" @default.
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- W2040475019 doi "https://doi.org/10.1021/cg8006712" @default.
- W2040475019 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2724020" @default.
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