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• W2040478283 abstract "Reaction of the pentaosmium-carbido dianion [Os5C(CO)14]2−,1 with [Os(C6H6)(MeCN)3]2+ gave[Os6C(CO)14(η6-C6H6)]2 in fair yield; while the corresponding reaction with [Ru(C6H6)(MeCN)3]2+ gave[RuOs5C(CO)14(η6-C6H6)]3 in moderate yield. Treatment of3 with carbon monoxide produces an unstable species[RuOs5C(CO)15(η6-C6H6)]4a, which on standing in CH2Cl2 undergoes fragmentation to give the species[RuOs4C(CO)12(η6-C6H6)]4b or decarbonylation to3. Clusters2, 3 and4b have been fully characterised by both spectroscopic and crystallographic methods. The X-ray structure analysis shows that both2 and3 are isomorphous. Both molecules contain an octahedral cavity accomodating an interstitial C(carbide) atom, with theη6-C6H6 coordinated to the Ru or Os atom in an apical position. Cluster4b is an unprecedented pentanuclear osmium-ruthenium mixed-metal carbido cluster containing anη6-coordinated benzene ligand." @default.
• W2040478283 created "2016-06-24" @default.
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• W2040478283 date "1996-11-01" @default.
• W2040478283 modified "2023-10-14" @default.
• W2040478283 title "Hexanuclear and pentanuclear benzene carbido clusters: synthesis, characterisation and molecular structures of[Os6C(CO)14(η6-C6H6)],[RuOs5C(CO)14(η6-C6H6)]and[RuOs4C(CO)12(η6-C6H6)]" @default.
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• W2040478283 doi "https://doi.org/10.1016/s0022-328x(96)06394-2" @default.
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