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- W2040487237 abstract "Bei der Hydrierung von 3,5-Dihydroxybenzylalkohol (5) mit Raney-Nickel entsteht ein Gemisch aus 5-Hydroxymethyldihydroresorcin (6) und 5-Methyldihydroresorcin (8); in Spuren ist auser-dem 5-Methylresorcin (= Orcin, 7) nachweisbar. Die Struktur von 6 wird durch die unabhangige Reaktionsfolge 9 16 bewiesen, wobei 6 aus dessen Benzylether 16 durch selektive Hydrogenolyse entsteht.Selective Catalytic Hydrogenations and Hydrogenolyses, I: Synthesis of 5-(Hydroxymethyl)dihydroresorcinolHydrogenation of 3,5-dihydroxybenzyl alcohol (5) with Raney nickel yields a mixture of 5-(hydroxymethyl)dihydroresorcinol (6) and 5-methyldihydroresorcinol (8); besides, 5-methylresorcinol (= orcinol, 7) is formed in traces. The structure of 6 is proved by an independent sequence of reactions 9 16 which includes the selective hydrogenolysis of the benzyl ether 16 to the title compound 6." @default.
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- W2040487237 date "1979-01-01" @default.
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- W2040487237 title "Selektive katalytische Hydrierungen und Hydrogenolysen, 1. Mitt. Synthese von 5-Hydroxymethyldihydroresorcin" @default.
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- W2040487237 doi "https://doi.org/10.1002/ardp.19793120310" @default.
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