Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040488465> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2040488465 endingPage "472" @default.
- W2040488465 startingPage "467" @default.
- W2040488465 abstract "Synthesis of N-Alkyl-arylamines by Thermolysis or Photolysis of 3-Alkyl-1,3-bis(p-chlorophenyl)triazenes The thermolysis of 3-alkyl-1,3-bis(p-chlorophenyl)triazenes in benzene or methanol leads to the formation of N-alkyl-p-chloroanilines (2) in 19–50% yield, N-alkyl-bis(p-chlorophenyl)amines (3) in 7.5–15.5% yield and 4,4′-dichlorobiphenyle (4) in 1–7% yield; besides with benzene as the substrate, 4-chlorobiphenyle (5) (12–20% yield) was also formed. The photolysis in methanol gives only the N-alkyl-p-chloroanilines (2) in 32–40% yield. In these two cases the results are consistent with a radical pair formation in a solvent cage, recombination (thermolysis) and/or diffusion (thermolysis and photolysis) with intermolecular abstraction of hydrogen. A free radical chain mechanism is involved in the photolytic process and the quantum yield is high." @default.
- W2040488465 created "2016-06-24" @default.
- W2040488465 creator A5007151964 @default.
- W2040488465 creator A5040888077 @default.
- W2040488465 creator A5048331667 @default.
- W2040488465 date "1980-03-05" @default.
- W2040488465 modified "2023-09-25" @default.
- W2040488465 title "Synthèse deN-Alkyl-arylamines par Thermolyse ou Photolyse d'Alkyl-3-diaryl-1,3-triazènes" @default.
- W2040488465 cites W1985875503 @default.
- W2040488465 cites W2056179435 @default.
- W2040488465 cites W2069989968 @default.
- W2040488465 cites W4244561172 @default.
- W2040488465 cites W4245545343 @default.
- W2040488465 doi "https://doi.org/10.1002/hlca.19800630217" @default.
- W2040488465 hasPublicationYear "1980" @default.
- W2040488465 type Work @default.
- W2040488465 sameAs 2040488465 @default.
- W2040488465 citedByCount "8" @default.
- W2040488465 countsByYear W20404884652014 @default.
- W2040488465 countsByYear W20404884652017 @default.
- W2040488465 crossrefType "journal-article" @default.
- W2040488465 hasAuthorship W2040488465A5007151964 @default.
- W2040488465 hasAuthorship W2040488465A5040888077 @default.
- W2040488465 hasAuthorship W2040488465A5048331667 @default.
- W2040488465 hasConcept C121332964 @default.
- W2040488465 hasConcept C134121241 @default.
- W2040488465 hasConcept C155647269 @default.
- W2040488465 hasConcept C160434732 @default.
- W2040488465 hasConcept C171001562 @default.
- W2040488465 hasConcept C178790620 @default.
- W2040488465 hasConcept C185592680 @default.
- W2040488465 hasConcept C191897082 @default.
- W2040488465 hasConcept C192562407 @default.
- W2040488465 hasConcept C2777691172 @default.
- W2040488465 hasConcept C2779607525 @default.
- W2040488465 hasConcept C2780263894 @default.
- W2040488465 hasConcept C54582936 @default.
- W2040488465 hasConcept C62520636 @default.
- W2040488465 hasConcept C75473681 @default.
- W2040488465 hasConcept C91881484 @default.
- W2040488465 hasConceptScore W2040488465C121332964 @default.
- W2040488465 hasConceptScore W2040488465C134121241 @default.
- W2040488465 hasConceptScore W2040488465C155647269 @default.
- W2040488465 hasConceptScore W2040488465C160434732 @default.
- W2040488465 hasConceptScore W2040488465C171001562 @default.
- W2040488465 hasConceptScore W2040488465C178790620 @default.
- W2040488465 hasConceptScore W2040488465C185592680 @default.
- W2040488465 hasConceptScore W2040488465C191897082 @default.
- W2040488465 hasConceptScore W2040488465C192562407 @default.
- W2040488465 hasConceptScore W2040488465C2777691172 @default.
- W2040488465 hasConceptScore W2040488465C2779607525 @default.
- W2040488465 hasConceptScore W2040488465C2780263894 @default.
- W2040488465 hasConceptScore W2040488465C54582936 @default.
- W2040488465 hasConceptScore W2040488465C62520636 @default.
- W2040488465 hasConceptScore W2040488465C75473681 @default.
- W2040488465 hasConceptScore W2040488465C91881484 @default.
- W2040488465 hasIssue "2" @default.
- W2040488465 hasLocation W20404884651 @default.
- W2040488465 hasOpenAccess W2040488465 @default.
- W2040488465 hasPrimaryLocation W20404884651 @default.
- W2040488465 hasRelatedWork W1989313657 @default.
- W2040488465 hasRelatedWork W2046259802 @default.
- W2040488465 hasRelatedWork W2071871725 @default.
- W2040488465 hasRelatedWork W2078872411 @default.
- W2040488465 hasRelatedWork W2081197054 @default.
- W2040488465 hasRelatedWork W2087172842 @default.
- W2040488465 hasRelatedWork W2951672655 @default.
- W2040488465 hasRelatedWork W2952329622 @default.
- W2040488465 hasRelatedWork W2952979462 @default.
- W2040488465 hasRelatedWork W2522651014 @default.
- W2040488465 hasVolume "63" @default.
- W2040488465 isParatext "false" @default.
- W2040488465 isRetracted "false" @default.
- W2040488465 magId "2040488465" @default.
- W2040488465 workType "article" @default.