FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040518977> ?p ?o ?g. }

• W2040518977 endingPage "134" @default.
• W2040518977 startingPage "130" @default.
• W2040518977 abstract "Hydrogen bonding has been proposed as the triggering mechanism for the sorption of lanthanide ions by polymer-supported tetramethylmalonamide (TMMA) and diethylenetriamine (DETA) – substituted malonate ester. In the current study, DETA was immobilized onto cross-linked poly(vinylbenzyl chloride), converted to the urea, and its affinity determined for lanthanide ions from solutions of 2–8 M HCl. Lanthanide affinities significantly increase when the acid concentration exceeds 4 M. The site at which sorption occurs forms after protonation of the carbonyl, stabilization by hydrogen bonding to the interior nitrogen and resultant formation of an iminium ion. This is consistent with the mechanism proposed for the amide polymers. TMMA has the weakest affinities for Ln(III) ions yet is most selective due to attenuation of the (+) charge at the iminium site by two electron-donating methyl groups (=NR2(+)); DETA-malonamide (MAm) has higher Ln(III) affinities than TMMA but is less selective because the iminium has only one –CH2- moiety attenuating the (+) charge (=NHR(+)); the urea also forms a secondary iminium but its higher basicity makes its iminium more positively charged than that in DETA–MAm and therefore a stronger ligand. The urea has the highest affinities and is unique in having the lanthanide distribution coefficients correlate with the sum of the first, second and third ionization energies. The implication of this for the sorption mechanism is discussed." @default.
• W2040518977 created "2016-06-24" @default.
• W2040518977 creator A5020225533 @default.
• W2040518977 creator A5079865531 @default.
• W2040518977 date "2012-08-01" @default.
• W2040518977 modified "2023-10-16" @default.
• W2040518977 title "Polymer-supported urea: The effect of hydrogen bonding on lanthanide ion affinities" @default.
• W2040518977 cites W1964963909 @default.
• W2040518977 cites W1970254662 @default.
• W2040518977 cites W1975937789 @default.
• W2040518977 cites W1980776144 @default.
• W2040518977 cites W1983901698 @default.
• W2040518977 cites W1991897421 @default.
• W2040518977 cites W1997650665 @default.
• W2040518977 cites W1999986548 @default.
• W2040518977 cites W2008364521 @default.
• W2040518977 cites W2008892731 @default.
• W2040518977 cites W2010403948 @default.
• W2040518977 cites W2023994663 @default.
• W2040518977 cites W2026720556 @default.
• W2040518977 cites W2031719780 @default.
• W2040518977 cites W2032064408 @default.
• W2040518977 cites W2041856163 @default.
• W2040518977 cites W2052160968 @default.
• W2040518977 cites W2055248171 @default.
• W2040518977 cites W2064785304 @default.
• W2040518977 cites W2066548633 @default.
• W2040518977 cites W2074353606 @default.
• W2040518977 cites W2079779417 @default.
• W2040518977 cites W2086321846 @default.
• W2040518977 cites W2091191403 @default.
• W2040518977 cites W2144045675 @default.
• W2040518977 cites W2146152886 @default.
• W2040518977 cites W2151037107 @default.
• W2040518977 cites W2333330524 @default.
• W2040518977 cites W2949209604 @default.
• W2040518977 doi "https://doi.org/10.1016/j.ica.2012.05.011" @default.
• W2040518977 hasPublicationYear "2012" @default.
• W2040518977 type Work @default.
• W2040518977 sameAs 2040518977 @default.
• W2040518977 citedByCount "1" @default.
• W2040518977 countsByYear W20405189772023 @default.
• W2040518977 crossrefType "journal-article" @default.
• W2040518977 hasAuthorship W2040518977A5020225533 @default.
• W2040518977 hasAuthorship W2040518977A5079865531 @default.
• W2040518977 hasConcept C112887158 @default.
• W2040518977 hasConcept C116569031 @default.
• W2040518977 hasConcept C145148216 @default.
• W2040518977 hasConcept C170493617 @default.
• W2040518977 hasConcept C178790620 @default.
• W2040518977 hasConcept C179104552 @default.
• W2040518977 hasConcept C185592680 @default.
• W2040518977 hasConcept C188027245 @default.
• W2040518977 hasConcept C201770740 @default.
• W2040518977 hasConcept C2776568683 @default.
• W2040518977 hasConcept C2778439535 @default.
• W2040518977 hasConcept C2778567177 @default.
• W2040518977 hasConcept C2780283098 @default.
• W2040518977 hasConcept C2780302063 @default.
• W2040518977 hasConcept C30095370 @default.
• W2040518977 hasConcept C32909587 @default.
• W2040518977 hasConcept C55493867 @default.
• W2040518977 hasConcept C71240020 @default.
• W2040518977 hasConceptScore W2040518977C112887158 @default.
• W2040518977 hasConceptScore W2040518977C116569031 @default.
• W2040518977 hasConceptScore W2040518977C145148216 @default.
• W2040518977 hasConceptScore W2040518977C170493617 @default.
• W2040518977 hasConceptScore W2040518977C178790620 @default.
• W2040518977 hasConceptScore W2040518977C179104552 @default.
• W2040518977 hasConceptScore W2040518977C185592680 @default.
• W2040518977 hasConceptScore W2040518977C188027245 @default.
• W2040518977 hasConceptScore W2040518977C201770740 @default.
• W2040518977 hasConceptScore W2040518977C2776568683 @default.
• W2040518977 hasConceptScore W2040518977C2778439535 @default.
• W2040518977 hasConceptScore W2040518977C2778567177 @default.
• W2040518977 hasConceptScore W2040518977C2780283098 @default.
• W2040518977 hasConceptScore W2040518977C2780302063 @default.
• W2040518977 hasConceptScore W2040518977C30095370 @default.
• W2040518977 hasConceptScore W2040518977C32909587 @default.
• W2040518977 hasConceptScore W2040518977C55493867 @default.
• W2040518977 hasConceptScore W2040518977C71240020 @default.
• W2040518977 hasLocation W20405189771 @default.
• W2040518977 hasOpenAccess W2040518977 @default.
• W2040518977 hasPrimaryLocation W20405189771 @default.
• W2040518977 hasRelatedWork W1486029465 @default.
• W2040518977 hasRelatedWork W1534726502 @default.
• W2040518977 hasRelatedWork W1972603991 @default.
• W2040518977 hasRelatedWork W1975937789 @default.
• W2040518977 hasRelatedWork W1999386611 @default.
• W2040518977 hasRelatedWork W2118634077 @default.
• W2040518977 hasRelatedWork W2143553309 @default.
• W2040518977 hasRelatedWork W2479462601 @default.
• W2040518977 hasRelatedWork W2581688650 @default.
• W2040518977 hasRelatedWork W2605032758 @default.
• W2040518977 hasVolume "391" @default.
• W2040518977 isParatext "false" @default.
• W2040518977 isRetracted "false" @default.
• W2040518977 magId "2040518977" @default.

• next