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- W2040531131 startingPage "A978" @default.
- W2040531131 abstract "The ${mathrm{V}}^{51}$ NMR frequency shift ($frac{ensuremath{Delta}ensuremath{nu}}{ensuremath{nu}}$) in metallic ${mathrm{V}}_{2}$${mathrm{O}}_{3}$ has been measured in the temperature range of 175 to 575ifmmode^circelsetextdegreefi{}K the frequency shift at these two temperatures being -0.61% and +0.1%, respectively. Various contributions to the frequency shift and magnetic susceptibility are determined by constructing a ($frac{ensuremath{Delta}ensuremath{nu}}{ensuremath{nu}}$)-versus-$ensuremath{chi}$ diagram. The $d$-band spin susceptibility ${ensuremath{chi}}_{d}$ is found to obey a Curie-Weiss law down to the transition temperature of about 160ifmmode^circelsetextdegreefi{}K. A large temperature-independent orbital susceptibility is found to be ${ensuremath{chi}}_{mathrm{VV}}ensuremath{simeq}1.52%$. From the temperature dependence of ${ensuremath{chi}}_{d}(T)$ and the corresponding frequency shift ${(frac{ensuremath{Delta}ensuremath{nu}}{ensuremath{nu}})}_{d}$, a negative hyperfine field of ${{H}_{d}}^{mathrm{hf}}ensuremath{simeq}ensuremath{-}140$ kOe/Bohr magneton, resulting from core polarization, a temperature-dependent orbital hyperfine field, and a dipolar hyperfine field, is found. With decreasing temperature the ${mathrm{V}}^{51}$ NMR signal abruptly disappears at the transition temperature, suggesting that ${mathrm{V}}_{2}$${mathrm{O}}_{3}$ undergoes antiferromagnetic ordering for temperatures less than 160ifmmode^circelsetextdegreefi{}K. Contributions to the ${mathrm{V}}^{51}$ NMR linewidth are discussed." @default.
- W2040531131 created "2016-06-24" @default.
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- W2040531131 date "1965-02-01" @default.
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- W2040531131 title "Contributions to the<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>V</mml:mi></mml:mrow><mml:mrow><mml:mn>51</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>Nuclear Magnetic Resonance Frequency Shift and Susceptibility in Vanadium Sesquioxide" @default.
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- W2040531131 doi "https://doi.org/10.1103/physrev.137.a978" @default.
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