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- W2040552783 abstract "Studies on the regioselectivities for the Sharpless asymmetric dihydroxylation (AD) of conjugated dienoates, trienoates, dienones and dienamides are described. Excellent regioselectivities were obtained in straight chain dienoates, all trienoates, ketones and amides. The remote branched iso-propyl and tert-butyl groups of dienoates greatly lowered the normally excellent regiocontrol. This observation is rationalized in terms of substrate conformational changes, and the steric interaction between the branched methyl group of iso-propyl or tert-butyl groups and the ethyl group on the (DHQD)2PHAL ligand." @default.
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- W2040552783 date "2005-06-01" @default.
- W2040552783 modified "2023-09-24" @default.
- W2040552783 title "Remote steric effect on the regioselectivity of Sharpless asymmetric dihydroxylation" @default.
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- W2040552783 doi "https://doi.org/10.1016/j.tet.2005.03.119" @default.
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