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- W2040554729 abstract "This communication describes the desymmetrization of various achiral metallated cyclohexadienes with a series of chiral N-tert-butanesulfinyl imines. Depending on the metal used, either the symmetrical diene (dicyclohexadienyl-zinc) or the desymmetrized diene (cyclohexadienyl-MgCl) is obtained in a good regioselectivity with excellent diastereoselectivity. The products formed should be useful building blocks for natural product synthesis. The symmetrical 1,4-dienes are readily oxidized to the corresponding diarylmethylamine derivatives." @default.
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- W2040554729 date "2008-04-09" @default.
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- W2040554729 title "Desymmetrization of Metallated Cyclohexadienes with Chiral <i>N-tert</i>-Butanesulfinyl Imines" @default.
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- W2040554729 doi "https://doi.org/10.1021/ol800478q" @default.
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