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- W2040562722 abstract "Die Kristallstruktur der hexagonal in der Raumgruppe P62,–D krikristallisierenden Verbindung CsCrF4 wurde bestimmt: a = 9,650(5), c = 3,857(3) Å, V = 311,1 Å3, z = 3, R = 0,023 für 220 symmetrieunabhängige Reflexe hkl. CsCrF4 stellt eine neuen Typ von Kettenstruktur dar, in dem drei längs [001] über trans-Ecken verknüpfte Oktaederketten miteinander über cis-Ecken zu einem Dreierstrang verbunden sind. Die Brückenwinkel betragen CrFCr 177,9° bzw. 149,3°, die entsprechenden Abstände CrF = 1,929 bzw. 1,940 Ä, gegenüber 1,851 Å für die terminalen Liganden. Die Ergebnisse werden diskutiert und Beziehungen zu anderen Strukturen aufgezeigt. Structures of Fluorides with Caesium. IV. The Crystal Structure of CsCrF4 – a Novel Tetra-fluorometallate Type with Chain Structure The crystal structure of the hexagonal compound CsCrF4, crystallizing in space group P62m–D, was determined: a =9.650(5), c = 3.857(3) Å, z = 3, R = 0.023 for 220 symmetrically independent reflections hkl. CsCrF4 is a new type of chain structure, containing three chains of octahedra sharing trans corners along [001] and connected by cis corners to form a triple chain. The bridging angles are CrFCr = 177.9° and 149.3°, the corresponding distances CrF = 1.929 and 1.940 Å, resp., compared to 1.851 Å for the terminal ligands. The results are discussed and relations to other structures shown." @default.
- W2040562722 created "2016-06-24" @default.
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- W2040562722 date "1978-07-01" @default.
- W2040562722 modified "2023-09-24" @default.
- W2040562722 title "Strukturen caesiumhaltiger Fluoride. IV. Die KristallStruktur von CsCrF4 - ein neuer Tetrafluorometallat-Typ mit Kettenstruktur" @default.
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- W2040562722 doi "https://doi.org/10.1002/zaac.19784420119" @default.
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