FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040569977> ?p ?o ?g. }

• W2040569977 endingPage "84" @default.
• W2040569977 startingPage "77" @default.
• W2040569977 abstract "Three 2,3,22,23,24-pentahydro-21H-biline-1,19-dion-10-enium salts have been prepared: 17,18,22,23-tetramethyl-2,3,22,23,24-pentahydro-21H-biline-1,19-dion-10-enium methanesulphonate (1) with a central flexible structure, its 10-syn-locked 22,23-methylene homologue (2) with a central Z-syn structure and its 8,12-isopropylidene homologue (3), the first bile pigment with a central E-anti structure. For comparison, the corresponding E-anti 22,23,24-trihydrobilinedionium salt 3a was also prepared. The 2,3 single bond induces a more delocalized charged system, having higher fluorescence quantum yields than observed for the fully conjugated systems. The flexible systems 1, 1a, which adopt an E-anti conformation, do not show fluorescence. The E-anti systems have a larger Stokes shift than do the Z-syn systems. In the pentahydrobilinedionium salts, the highest positive charge resides on the central C10 atom as apparent from 1H NMR spectroscopy and as was corroborated by the finding that the site of nucleophilic attack is invariably at C10. The pentahydro salts also undergo electrophilic H-D exchange at positions 5, 7 and 12. From the spectral data presented it would appear that the chromophore in (allo)phycocyanine will occur as a protonated system in a rigid protein environment in the E-anti conformation." @default.
• W2040569977 created "2016-06-24" @default.
• W2040569977 creator A5000259808 @default.
• W2040569977 creator A5041368706 @default.
• W2040569977 creator A5072260041 @default.
• W2040569977 creator A5080887212 @default.
• W2040569977 creator A5082027918 @default.
• W2040569977 date "2010-09-02" @default.
• W2040569977 modified "2023-09-23" @default.
• W2040569977 title "The synthesis, properties and reactivity of model systems for protonated chromophores in biliproteins" @default.
• W2040569977 cites W1985161556 @default.
• W2040569977 cites W1991600179 @default.
• W2040569977 cites W2027094375 @default.
• W2040569977 cites W2031995223 @default.
• W2040569977 cites W2035703111 @default.
• W2040569977 cites W2060366308 @default.
• W2040569977 cites W2073588923 @default.
• W2040569977 cites W2077508303 @default.
• W2040569977 cites W2086954853 @default.
• W2040569977 cites W2622720714 @default.
• W2040569977 cites W4255671808 @default.
• W2040569977 cites W599773689 @default.
• W2040569977 doi "https://doi.org/10.1002/recl.19871060303" @default.
• W2040569977 hasPublicationYear "2010" @default.
• W2040569977 type Work @default.
• W2040569977 sameAs 2040569977 @default.
• W2040569977 citedByCount "6" @default.
• W2040569977 countsByYear W20405699772019 @default.
• W2040569977 crossrefType "journal-article" @default.
• W2040569977 hasAuthorship W2040569977A5000259808 @default.
• W2040569977 hasAuthorship W2040569977A5041368706 @default.
• W2040569977 hasAuthorship W2040569977A5072260041 @default.
• W2040569977 hasAuthorship W2040569977A5080887212 @default.
• W2040569977 hasAuthorship W2040569977A5082027918 @default.
• W2040569977 hasConcept C112613896 @default.
• W2040569977 hasConcept C121332964 @default.
• W2040569977 hasConcept C142724271 @default.
• W2040569977 hasConcept C145148216 @default.
• W2040569977 hasConcept C155647269 @default.
• W2040569977 hasConcept C158711907 @default.
• W2040569977 hasConcept C161790260 @default.
• W2040569977 hasConcept C178790620 @default.
• W2040569977 hasConcept C178907741 @default.
• W2040569977 hasConcept C185592680 @default.
• W2040569977 hasConcept C192468462 @default.
• W2040569977 hasConcept C204787440 @default.
• W2040569977 hasConcept C2776910235 @default.
• W2040569977 hasConcept C2777454769 @default.
• W2040569977 hasConcept C30095370 @default.
• W2040569977 hasConcept C50027330 @default.
• W2040569977 hasConcept C521977710 @default.
• W2040569977 hasConcept C62520636 @default.
• W2040569977 hasConcept C66974803 @default.
• W2040569977 hasConcept C70050531 @default.
• W2040569977 hasConcept C71240020 @default.
• W2040569977 hasConcept C71924100 @default.
• W2040569977 hasConcept C75473681 @default.
• W2040569977 hasConcept C8010536 @default.
• W2040569977 hasConcept C91881484 @default.
• W2040569977 hasConceptScore W2040569977C112613896 @default.
• W2040569977 hasConceptScore W2040569977C121332964 @default.
• W2040569977 hasConceptScore W2040569977C142724271 @default.
• W2040569977 hasConceptScore W2040569977C145148216 @default.
• W2040569977 hasConceptScore W2040569977C155647269 @default.
• W2040569977 hasConceptScore W2040569977C158711907 @default.
• W2040569977 hasConceptScore W2040569977C161790260 @default.
• W2040569977 hasConceptScore W2040569977C178790620 @default.
• W2040569977 hasConceptScore W2040569977C178907741 @default.
• W2040569977 hasConceptScore W2040569977C185592680 @default.
• W2040569977 hasConceptScore W2040569977C192468462 @default.
• W2040569977 hasConceptScore W2040569977C204787440 @default.
• W2040569977 hasConceptScore W2040569977C2776910235 @default.
• W2040569977 hasConceptScore W2040569977C2777454769 @default.
• W2040569977 hasConceptScore W2040569977C30095370 @default.
• W2040569977 hasConceptScore W2040569977C50027330 @default.
• W2040569977 hasConceptScore W2040569977C521977710 @default.
• W2040569977 hasConceptScore W2040569977C62520636 @default.
• W2040569977 hasConceptScore W2040569977C66974803 @default.
• W2040569977 hasConceptScore W2040569977C70050531 @default.
• W2040569977 hasConceptScore W2040569977C71240020 @default.
• W2040569977 hasConceptScore W2040569977C71924100 @default.
• W2040569977 hasConceptScore W2040569977C75473681 @default.
• W2040569977 hasConceptScore W2040569977C8010536 @default.
• W2040569977 hasConceptScore W2040569977C91881484 @default.
• W2040569977 hasIssue "3" @default.
• W2040569977 hasLocation W20405699771 @default.
• W2040569977 hasOpenAccess W2040569977 @default.
• W2040569977 hasPrimaryLocation W20405699771 @default.
• W2040569977 hasRelatedWork W1977994322 @default.
• W2040569977 hasRelatedWork W1981069732 @default.
• W2040569977 hasRelatedWork W1995843503 @default.
• W2040569977 hasRelatedWork W2040765698 @default.
• W2040569977 hasRelatedWork W2085837863 @default.
• W2040569977 hasRelatedWork W2146825015 @default.
• W2040569977 hasRelatedWork W2516794653 @default.
• W2040569977 hasRelatedWork W2590720850 @default.
• W2040569977 hasRelatedWork W2977677727 @default.
• W2040569977 hasRelatedWork W4321638626 @default.

• next