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- W2040572877 startingPage "1775" @default.
- W2040572877 abstract "Europium decavanadate, [Eu(H2O)8]2[V10O28]·8H2O, crystallizes in triclinic, , a = 9.413(1), b = 9.885(1), c = 23.556(4)Å, α = 81.31(2), β = 82.08(2), γ = 89.51(2)°, V = 2145.8(5)Å3, Z = 2. There are two crystallographically independent [Eu(H2O)8]3+ cations and two centrosymmetric [V10O28]6− anions in a unit cell. Each [Eu(H2O)8]3+ cation achieves eight-fold coordination by aqua-ligands with an approximately square-antiprismatic configuration. The Eu–O distances for the [Eu(H2O)8]3+ cations were found to be 2.38(1)—2.54(1) Å (mean 2.44 ± 0.02 Å). The crystal structure consists of two crystallographically inequivalent [Eu(H2O)8]2[V10O28] layers and interstitial water molecules, the former being piled up alternately along the c-direction, and the latter linking the two adjacent layers with hydrogen-bonds." @default.
- W2040572877 created "2016-06-24" @default.
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- W2040572877 date "1999-08-01" @default.
- W2040572877 modified "2023-09-24" @default.
- W2040572877 title "X-Ray Structural Characterization of [Eu(H<sub>2</sub>O)<sub>8</sub>]<sub>2</sub>[V<sub>10</sub>O<sub>28</sub>]·8H<sub>2</sub>O" @default.
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- W2040572877 doi "https://doi.org/10.1246/bcsj.72.1775" @default.
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