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• W2040576827 startingPage "532" @default.
• W2040576827 abstract "Difluorocarbene derived from various carbene precursors could be effectively decomposed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). This decomposition process was successfully applied in the subsequent trifluoromethylation of a variety of (hetero)aryl iodides without the addition of an external fluoride ion. Mechanistic investigation revealed the detailed difluorocarbene conversion process in which the decomposed difluorocarbene is finally transformed into a fluoride ion and carbon monoxide." @default.
• W2040576827 created "2016-06-24" @default.
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• W2040576827 date "2015-01-14" @default.
• W2040576827 modified "2023-10-17" @default.
• W2040576827 title "1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation" @default.
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• W2040576827 doi "https://doi.org/10.1021/ol503548s" @default.
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