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- W2040592618 abstract "Oxygen isotope exchange between minerals and hydrothermal waters can occur by means of solution—precipitation, chemical reaction, or diffusion. Further, minerals are known to exchange oxygen isotopes faster in the presence of water than when dry. Careful laboratory measurement of exchange rates by diffusion has been effected. The large differences in values of diffusion coefficients for different diffusing species in one mineral, the trivially small free-energy change for reaction involving only isotope exchange, and the excellent fit of 18O concentration profiles to a diffusion relation, all combine to demonstrate the diffusion process. The same diffusion coefficients are obtained whether the natural mineral sample is in contact with +80‰ (SMOW) water, or with 40% 18O water. Diffusion must happen if the mineral is above its closure temperature, although exchange will only occur if another phase is available with which it can exchange. The use of a “compensation law” to assess the validity of experimental data is, strictly speaking, limited to cases where the same diffusion mechanism is operating for the different diffusing species being compared in a given mineral." @default.
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- W2040592618 date "1985-12-01" @default.
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- W2040592618 title "The nature of oxygen transport within minerals in the presence of hydrothermal water and the role of diffusion" @default.
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- W2040592618 doi "https://doi.org/10.1016/0009-2541(85)90069-5" @default.
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