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- W2040599275 abstract "Recently we have developed a convenient method for the synthesis of S -thioacyl dithiophosphates 1 , excellent thioacylating reagents. When hydroxylamines with one bulky group or two substituents on the nitrogen atom are treated with S -thioacyl dithiophosphates 1 O -thioacyl hydroxylamines 3 are produced exclusively. What is more important, compounds 3 undergo interesting reaction with dithiophosphoric acid 4 yielding amine and acyl thiophosphoryl disulfide 5 . The disulfide 5 can be formed as a product of thiophilic attack of the dithiophosphate anion on the thiocarbonyl group in protonated O -thioacyl hydroxylamine 3 . On the other hand, it is well known that dithiophosphate anions easily undergo one electron oxidation. Hence the dithiophosphate anion can act as single electron donor and disulfide 5 can be formed as a product of the SET reaction. The influence of light and radical traps strongly suggests that the second possibility operates in the reaction in focus." @default.
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- W2040599275 date "2002-06-01" @default.
- W2040599275 modified "2023-10-14" @default.
- W2040599275 title "May Dithiophosphoric Acid Participate in the SET Process?" @default.
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- W2040599275 doi "https://doi.org/10.1080/10426500212210" @default.
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