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• W2040610367 abstract "The mechanism of thermal stabilization of delithiated by cobalt substitution for nickel was closely studied from the structural point of view by thermogravimetry, X-ray diffraction, and X-ray absorption analysis. Delithiated with hexagonal or monoclinic structure was decomposed to a spinel phase (cubic, at temperatures around 220°C and then converted to a rock-salt phase (cubic, at higher temperatures. Cobalt substitution of nickel in stabilized the spinel phase, formed from the thermal decomposition of and suppressed the decomposition of this spinel phase to a rock-salt phase. While the highly delithiated was eventually converted to a rock salt phase with NiO structure during heating, spinel structure was locally formed around the cobalt ions in The improvement of the thermal stability of highly delithiated by cobalt addition could be explained by local formation of spinel structure around the cobalt ions in This spinel structure around the cobalt ions was relatively stable at high temperature and therefore, depressed the decomposition of to a rock-salt phase. © 2001 The Electrochemical Society. All rights reserved." @default.
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• W2040610367 date "2001-01-01" @default.
• W2040610367 modified "2023-10-14" @default.
• W2040610367 title "A Mechanistic Study on the Improvement of the Thermal Stability of Delithiated Li[sub 1−x]NiO[sub 2] by Co Substitution for Ni" @default.
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• W2040610367 doi "https://doi.org/10.1149/1.1402120" @default.
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