Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040612351> ?p ?o ?g. }
- W2040612351 endingPage "244" @default.
- W2040612351 startingPage "237" @default.
- W2040612351 abstract "In the present work, the equilibrium solubility of carbon dioxide (CO2) in mixtures of N-methyldiethanolamine (MDEA) and 1-butyl-3-methylimidazolium acetate ionic liquid ([bmim][acetate]) is measured at temperatures (303.15 to 343.15) K and over a pressure range of (0.1 to 3.9) MPa. The mass fraction compositions of the MDEA and [bmim][acetate] in the mixture are (0.3, 0.7) and (0.5, 0.5), respectively. The experimental results are presented as the partial pressure of CO2 against its molality (mol CO2 per kg of solvent) and mole fraction of CO2. Moreover, using the measured values, the enthalpy of solution for the CO2 solubility in the mixtures is calculated. Considering the present results at the given conditions, it is observed that replacing the aqueous media of the MDEA solution by [bmim][acetate] can reduce significantly the enthalpy of solution of CO2 in the solvent. For thermodynamic modelling, a new equation of state (PR-TS EoS) is extended by combining the Peng–Robinson (PR) equation of state as a cubic term for non-specific energy contribution and the Two-State Association Model (TSAM) for association energy contribution based on the frame of the cubic plus equation of state. Furthermore, the PR-TS EoS is applied to correlate the new experimental data of this work. To model the ternary (CO2 + MDEA + [bmim][acetate]) system, the parameters of the PR-TS EoS are first adjusted for the pure components. Subsequently, the solubility of CO2 in pure [bmim][acetate] is correlated so that the binary molecular interaction parameters for this binary sub system are optimised. Finally, the equilibrium solubility of CO2 in ternary mixture of {MDEA + [bmim][acetate]} correlates with the per cent average absolute deviation (AAD%) of 11.78 between the calculated and experimental partial pressure of CO2." @default.
- W2040612351 created "2016-06-24" @default.
- W2040612351 creator A5005555279 @default.
- W2040612351 creator A5047943522 @default.
- W2040612351 date "2015-02-01" @default.
- W2040612351 modified "2023-09-27" @default.
- W2040612351 title "High pressure measurement and thermodynamic modelling of the solubility of carbon dioxide in N-methyldiethanolamine and 1-butyl-3-methylimidazolium acetate mixture" @default.
- W2040612351 cites W1966814961 @default.
- W2040612351 cites W1967602766 @default.
- W2040612351 cites W1977509053 @default.
- W2040612351 cites W1979742905 @default.
- W2040612351 cites W1979872108 @default.
- W2040612351 cites W1982741233 @default.
- W2040612351 cites W1983045788 @default.
- W2040612351 cites W1992245880 @default.
- W2040612351 cites W1994349999 @default.
- W2040612351 cites W1998557914 @default.
- W2040612351 cites W2006747104 @default.
- W2040612351 cites W2008001354 @default.
- W2040612351 cites W2013293910 @default.
- W2040612351 cites W2013748968 @default.
- W2040612351 cites W2014464559 @default.
- W2040612351 cites W2016172486 @default.
- W2040612351 cites W2018026936 @default.
- W2040612351 cites W2018813307 @default.
- W2040612351 cites W2020502986 @default.
- W2040612351 cites W2022645262 @default.
- W2040612351 cites W2023152482 @default.
- W2040612351 cites W2025233477 @default.
- W2040612351 cites W2026210300 @default.
- W2040612351 cites W2026705682 @default.
- W2040612351 cites W2031965415 @default.
- W2040612351 cites W2034227736 @default.
- W2040612351 cites W2034800657 @default.
- W2040612351 cites W2037809631 @default.
- W2040612351 cites W2044083232 @default.
- W2040612351 cites W2044086422 @default.
- W2040612351 cites W2044585912 @default.
- W2040612351 cites W2045557804 @default.
- W2040612351 cites W2051352108 @default.
- W2040612351 cites W2052503487 @default.
- W2040612351 cites W2054717246 @default.
- W2040612351 cites W2054748396 @default.
- W2040612351 cites W2056324761 @default.
- W2040612351 cites W2057889467 @default.
- W2040612351 cites W2059830375 @default.
- W2040612351 cites W2065325021 @default.
- W2040612351 cites W2069106578 @default.
- W2040612351 cites W2069854835 @default.
- W2040612351 cites W2070227445 @default.
- W2040612351 cites W2075082326 @default.
- W2040612351 cites W2075579559 @default.
- W2040612351 cites W2076893020 @default.
- W2040612351 cites W2081985942 @default.
- W2040612351 cites W2091258245 @default.
- W2040612351 cites W2093725912 @default.
- W2040612351 cites W2100541277 @default.
- W2040612351 cites W2102004977 @default.
- W2040612351 cites W2103909145 @default.
- W2040612351 cites W2113461913 @default.
- W2040612351 cites W2129282293 @default.
- W2040612351 cites W2129288307 @default.
- W2040612351 cites W2132452883 @default.
- W2040612351 cites W2144143180 @default.
- W2040612351 cites W2153129612 @default.
- W2040612351 cites W2156458670 @default.
- W2040612351 cites W2162620636 @default.
- W2040612351 cites W2163318415 @default.
- W2040612351 cites W2317497556 @default.
- W2040612351 cites W2325214947 @default.
- W2040612351 cites W2334274439 @default.
- W2040612351 cites W3154881185 @default.
- W2040612351 doi "https://doi.org/10.1016/j.jct.2014.10.011" @default.
- W2040612351 hasPublicationYear "2015" @default.
- W2040612351 type Work @default.
- W2040612351 sameAs 2040612351 @default.
- W2040612351 citedByCount "23" @default.
- W2040612351 countsByYear W20406123512015 @default.
- W2040612351 countsByYear W20406123512016 @default.
- W2040612351 countsByYear W20406123512017 @default.
- W2040612351 countsByYear W20406123512018 @default.
- W2040612351 countsByYear W20406123512019 @default.
- W2040612351 countsByYear W20406123512020 @default.
- W2040612351 countsByYear W20406123512021 @default.
- W2040612351 countsByYear W20406123512022 @default.
- W2040612351 countsByYear W20406123512023 @default.
- W2040612351 crossrefType "journal-article" @default.
- W2040612351 hasAuthorship W2040612351A5005555279 @default.
- W2040612351 hasAuthorship W2040612351A5047943522 @default.
- W2040612351 hasConcept C116628846 @default.
- W2040612351 hasConcept C121332964 @default.
- W2040612351 hasConcept C147789679 @default.
- W2040612351 hasConcept C154881586 @default.
- W2040612351 hasConcept C155574463 @default.
- W2040612351 hasConcept C161790260 @default.
- W2040612351 hasConcept C16946580 @default.
- W2040612351 hasConcept C170961132 @default.
- W2040612351 hasConcept C178790620 @default.