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- W2040647046 abstract "We have recorded high-resolution HeI and HeII photoelectron spectra of the valence bands of six MX2 compounds (M = Zn, Cd: X = Cl, Br, I) in the gas phase. Transition-state Xα SW calculations on all six compounds confirm the assignments. For the first time, we have clearly resolved the spin-orbit splitting of the IIg and IIu states in the bromide and iodide spectra: and calculated Πu splittings, using a simple MO LCAO model and the Dxh double group, are in very good agreement with the experimental values. The relative intensities of the photoelectron peaks change markedly from HeI to HeII spectra, and Xα SW cross section calculations on ZnCl2 predict these intensity changes rather well." @default.
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- W2040647046 date "1983-03-01" @default.
- W2040647046 modified "2023-09-25" @default.
- W2040647046 title "High-resolution HeI and HeII photoelectron spectra of the zinc and cadmium dihalide valence bands" @default.
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- W2040647046 doi "https://doi.org/10.1016/0301-0104(83)85025-3" @default.
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