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• W2040668869 abstract "Two anomeric nucleosides with tricyclic carbohydrate moieties, 3 and 14, are synthesised in 11 steps from diacetone-D-glucose, taking advantage of a stereoselective Grignard reaction, a stereoselective dihydroxylation and a regioselective tandem ring-closing procedure. The configuration of 3 is confirmed by measuring the 3JHH coupling constants in connection with molecular modelling and ab initio calculations, as these exclude alternative tricyclic nucleoside structures. The conformational preference for 3 is described. The furanose ring is found to be in an O-4′-endo conformation and the γ torsion angle in the +ap range." @default.
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• W2040668869 date "2000-01-01" @default.
• W2040668869 modified "2023-09-27" @default.
• W2040668869 title "Tricyclic nucleosides derived from D-glucose. Synthesis and conformational behaviour" @default.
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• W2040668869 doi "https://doi.org/10.1039/b006082h" @default.
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