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- W2040672004 abstract "Abstract Thirty four level anticrossing signals arising from the avoided crossing of ground-state rotational levels that differ in k by three or by six were observed in the CO2 laser Stark spectrum of POF3. Fifteen level crossing signals were also observed and were interpreted as resulting from the crossing of the k=0 and k= ± 3 levels in the ground state, which differ in M by one. These signals were analyzed together with laser-microwave double-resonance signals to obtain precise electric properties in the ground state. Values for the dipole moment μ0, the coefficients for the rotational dependence of the dipole moment μJ and μK, and the distortion dipole moment θxxx, with 2.5σ uncertainties in the parentheses, were determined as follows: μ0=1.868513(14) D, μJ=−.194(42)×10−6 D, μK=3.14(80)× 10−6 D, θxxx=0.586(140)× 10−6 D. Calibrated electric fields of the le and level anticrossing signals may serve as excellent standards for electric field measurement in CO2 laser Stark spectroscopy." @default.
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- W2040672004 date "1991-05-01" @default.
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- W2040672004 title "Observation of level crossing and level anticrossing signals in the CO2 laser Stark spectrum of POF3 and their proposed application to electric field standards in laser Stark spectroscopy" @default.
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- W2040672004 doi "https://doi.org/10.1016/0301-0104(91)85002-x" @default.
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