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- W2040692392 abstract "Abstract Previously recorded and published photoelectron spectroscopic data for mercury in the gas phase has been reanalyzed. The life-time broadenings have been determined for a large number of core levels. It is then seen that a recent detailed derivation of core-level line-widths based on X-ray emission spectroscopy give life-time widths that are generally too large. The 4d 3/2 4d 5/2 nd Coster–Kronig (CK) transition is also discussed. We find that the additional broadening of the 4d 3/2 level for mercury metal is indeed due to a CK decay, in contrast to recent claims. In atomic mercury, however, the CK process in energetically forbidden. In spite of this we find that the 4d 3/2 level is broadened also in this case. We propose that this is due to a mixing between the 4d 3/2 hole state and discrete 4d 5/2 nd states." @default.
- W2040692392 created "2016-06-24" @default.
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- W2040692392 date "2015-07-01" @default.
- W2040692392 modified "2023-10-17" @default.
- W2040692392 title "New determination of the core-level life-time broadenings in mercury" @default.
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- W2040692392 doi "https://doi.org/10.1016/j.elspec.2015.01.002" @default.
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