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- W2040693063 abstract "X-ray crystal structure analysis revealed the absolute configuration of compound 2 and thus proved the absolute configuration of 5-deazaflavin (+)-1 possessing both axial and planar chirality to be (S). Model reactions of “(net) hydride transfer” between 1 and Me2PNPH enanatiomers revealed that (S)-(+)-1 oxidizes (4S)-Me2PNPH more rapidly than its (4R) isomer and that (R)-(−)-1 oxidizes (4R)-Me2PNPH more rapidly than its (4S) isomer. These results strongly suggest that an enatioselectivity on Me2PNPH by chiral 1 is not solely determined by the availability of C(4) hydrogen but by the “(net) hydride donor-acceptor” interactions involving the interaction between the pyrimidine site of 5-deazaflavin molecule and the carbamoyl group of the NAD(P)H model as the important contributor." @default.
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- W2040693063 date "1994-11-01" @default.
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- W2040693063 title "Stereochemistry of asymmetric “(net) hydride transfer” in an intercoenzyme model reaction system" @default.
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- W2040693063 doi "https://doi.org/10.1016/s0040-4039(00)78456-5" @default.
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