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- W2040693742 endingPage "3165" @default.
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- W2040693742 abstract "Die Kristall- und Molekülstrukturen der Verbindungen 1–4 wurden aus Röntgendiffraktometer-Einkristalldaten bestimmt. In den acylischen Verbindungen betragen die P– N-Abstände 154.5 und 167.4 pm für 1 sowie 154.4 und 165.8 pm für 2 (Winkel N–P–N 108.4° bzw. 104.9°). Die cyclischen Verbindungen 3 und 4 enthalten jeweils gleich lange P-N-Bindungen (163.7 sowie 161.4 pm für 3 bzw. 4) als Folge delokalisierter pπ-pπ-Wechselwirkungen (Winkel N–P–N in 3 und 4 ca. 97°). Two-Coordinated Phosphorus(III) in Phosphorus-Nitrogen Compounds: Four Crystal and Molecular Structures The crystal structures of the compounds 1–4 were determined from single crystal X-ray data. The P-N bond lengths in the acylic compounds were found to be 154.5 and 167.4 pm for 1 and 154.4 and 165.8 pm for 2 (angle N–P–N 108.4°, respectively). The cyclic compounds 3 and 4 exhibit equal P–N bond lengths(163.7 pm for 3 and 161.4 pm for 4) due to electron delocalization in the pπ–pπ bonding systems (angle N–P–N 97° in both compounds)." @default.
- W2040693742 created "2016-06-24" @default.
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- W2040693742 date "1979-09-01" @default.
- W2040693742 modified "2023-10-06" @default.
- W2040693742 title "Zweifach koordinierter Phosphor(III) in Phosphor‐Stickstoff‐Verbindungen: vier Kristall‐ und Molekülstrukturen" @default.
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- W2040693742 doi "https://doi.org/10.1002/cber.19791120913" @default.
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