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- W2040694573 abstract "The rate of complex formation of Al(III) with semi-xylenol orange (SXO) in organic-aqueous mixtures exhibits a minimum value at a mole fraction of 0.01–0.02 of the organic component. The organic solvents studied are methanol, ethanol, n-butanol, acetone and dioxane. The minimum rate may be explained by a greater increase in the solvation of the initial state than the transition state for the reactants of oppositely charged reactants such as Al(III) and SXO, as a result of the destruction of the water structure by the small amount of organic solvent added. The value of the minimum rate and the critical mole fraction of organic solvent depend on the molecule size and the kind of solvent." @default.
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- W2040694573 date "1981-01-01" @default.
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- W2040694573 title "A critical minimum rate of aluminium(III) complex formation with semi-xylenol orange in organic and aqueous mixtures at a low mole fraction of organic component" @default.
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- W2040694573 doi "https://doi.org/10.1016/0022-1902(81)80276-x" @default.
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