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- W2040697898 abstract "New tertiary chloro-bis(1,2-N,N-dimethylaminomethylferrocenyl)stibine (1) and tris-(1,2-N,N-dimethylaminomethylferrocenyl)stibine ligand (2) containing CH2NMe2 pendenant arm at the ortho-position have been synthesized. Stibine (2) reacts with PtCl42− and hetero trimetallic cis-PtCl2L (3) complex is obtained, where stibine (2) acts as a bidentate ligand. All these compounds were characterized by various physicochemical methods and their molecular structures were determined by X-ray diffraction analyses. It is to be noted that tris(1,2-aminomethylferrocenyl)stibine represents the first example of a structurally characterized ferrocenyl pnictogen where three 1,2-disubstituted ferrocenyl groups are attached to the central antimony atom and phosphorus analogue of the stibine is missing in the literature. Stibine (1) shows a hypervalent Sb–N interaction while stibine (2) does not show this interaction in solid state." @default.
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- W2040697898 date "2008-10-01" @default.
- W2040697898 modified "2023-10-17" @default.
- W2040697898 title "Tris-(1,2-N,N-dimethylaminomethylferrocenyl)stibine and its heterotrimetallic complex" @default.
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- W2040697898 doi "https://doi.org/10.1016/j.jorganchem.2008.08.014" @default.
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