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- W2040698958 abstract "Abstract FTIR spectra of the linear, short-lived difluoroethyne molecule FCCF were recorded with a resolution ≦4 × 10 −3 cm −1 in the 1350 and 2150 cm −1 regions. Bands due to ν 3 , accompanied by the hot bands ( ν 3 + ν 4 ) − ν 4 and ( ν 3 + ν 5 ) − ν 5 , were detected and assigned in the former region, while in the latter region ν 2 + ν 3 , the hot bands with ν 4 and ν 5 and the difference band ( ν 1 - ν 5 ) were observed. Multiple anharmonic and rotational perturbations were detected and the strong anharmonic interaction of ν 3 with ( ν 2 + ν 4 + ν 5 ) 0 , W 2345 = 1.72202(4) cm −1 , which is accompanied by l -type resonance of the latter with ( ν 2 + ν 4 + ν 5 ) ±2 , was analyzed in detail. Rovibrational parameters of the v i = 1 states, i = 1 and 3–5, were obtained from the analysis of wavenumbers of more than 1500 transitions with J ≦ 124. Except for some heavily perturbed hot bands σ ( J ) of the fits ranged from 4 to 10 × 10 −4 cm −1 ." @default.
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- W2040698958 date "1992-01-01" @default.
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- W2040698958 title "The high-resolution infrared spectrum of FCCF: The 1350 and 2150 cm−1 regions" @default.
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- W2040698958 doi "https://doi.org/10.1016/0022-2852(92)90011-c" @default.
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