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- W2040700863 abstract "Abstract Pure and 2 mol% Sm2O3-doped ZrO2 nanopowders were synthesized via the precipitation method. The very lower activation energy (∼25.979 kJ/mol) related to the bulk counterpart is observed for the grain growth within the calcination temperature range of 600–1000 °C. Experimental results show that two factors were contributed to the lower activation energy of grain growth. Firstly, the introduction of oxygen vacancies in nano-2SmSZ grain surface reduces the activation energy of the formation of necks between grains. Secondly, the rotation process between coherent grains has very lower activation energy or even a zero-kinetic barrier." @default.
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- W2040700863 date "2004-10-01" @default.
- W2040700863 modified "2023-09-23" @default.
- W2040700863 title "Effect of nanocrystallite structure on the lower activation energy for Sm2O3-doped ZrO2" @default.
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- W2040700863 doi "https://doi.org/10.1016/j.molstruc.2004.05.010" @default.
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