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- W2040734956 abstract "Zone broadening of dissolved polystyrenes in packed-column hydrodynamic chromatography (HDC) was studied for a column filled with 1.5-μm monodisperse non-porous particles. The reduced plate heights were observed to be almost constant with mobile phase velocity for reduced mobile phase velocities in a range 2– > 150. In this velocity range, reduced plate heights well below 2 were obtained for polymer samples with molecular masses of 2200, 43 900 and 775 000. A comparison was made between measured plate heights and chromatographic theories of zone spreading. The effects of polymer size, polydispersity and polymer hydrodynamics on the measured plate heights are discussed." @default.
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- W2040734956 date "1993-03-01" @default.
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- W2040734956 title "Dispersion in packed-column hydrodynamic chromatography" @default.
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- W2040734956 doi "https://doi.org/10.1016/0021-9673(93)83001-9" @default.
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