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- W2040737598 abstract "Abstract The iterative chemoselective amination of cyanuric chloride to dimers of new G-2 dendritic N -substituted-2,4,6-triamino- s -triazines ( melamines ) having C-2-substituted 2-aminopropane-1,3-diols (‘ serinols ’) in tandem with the ethylene ketal of 4-piperidone as peripheral units is reported. The structure as a function of increasing molecular size was studied by NMR spectroscopy, DFT calculation and AFM imaging. A concise nomenclature defining the restricted rotational phenomena about the newly created C( s -triazine)–N(exocyclic) partial double bonds, seen as axes of (pro)diastereomerism, is used. We propose a new form of frontier rotamerism for the dendrimer surface, which operates over a long range." @default.
- W2040737598 created "2016-06-24" @default.
- W2040737598 creator A5004006480 @default.
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- W2040737598 date "2012-10-01" @default.
- W2040737598 modified "2023-10-17" @default.
- W2040737598 title "Design, synthesis and structure of new dendritic melamines. First use of a tandem C-2-substituted serinol—O,O-masked 4-piperidone as a peripheral unit in iterative synthesis" @default.
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