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- W2040739976 abstract "RhH(L)(PPh33 (L = CO or PF3) react with RCCR (R = CF3, or CO2Me) to give vinyl complexes trans-RH(L)(PPh3)2(CRCHR). These complexes undergo further acetylene insertion; e.g., trans Rh(L)(pph3)2(CR1CHR1) (R1 CF3) reacts with R2CCR2 (R2 = CO2Me) and transRh(L)(PPh3)2(CR2chr2) reacts wutg R1CCR1 to give unexpectedly the same double inserted product transRh(L)(PPh3(PPh3)2(CR2CR1CHR1) and a possible reaction mechanism is presented. Rh(PF3)(PPh3)2 [C(CF3)CHCF3] and tbutyl bromide give CF3CHCHCF3,isobutene and transRhBr(PPh3)2(PF3)." @default.
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- W2040739976 date "1979-01-01" @default.
- W2040739976 modified "2023-10-17" @default.
- W2040739976 title "Acetylene insertion and double insertion reactions of rhodium hydrido complexes" @default.
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- W2040739976 doi "https://doi.org/10.1016/s0022-328x(00)83126-5" @default.
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